Distribution of electrons in each
orbital governed by three rules
- Aufbau Principle
Charging electrons into each orbital / suborbital adapted to different levels of energy of each orbital
For example: 20Ca : 1s2 2s2 2p6
3s2 3p6 4s2
- Pauli Exclusion Principle
Each electron in the atoms just have 1 four
quantum numbers (n, l, m and z), if n, l, m equals then s must be different.
Order of orbitals (filling) in multi-electron atom
1s < 2s < 2p < 3s < 3p
< 4s < 3d < 4p < 5s < 4d < 5p < 6s
Fill lowest energy orbitals first (Aufbau principle)
Fill lowest energy orbitals first (Aufbau
principle)
Fill lowest energy orbitals first (Aufbau principle)
- . Hund’s Rule
Charging an electron into the orbital /
sub-orbital which has the equivalent energy levels may not form the pair first,
before orbital who have similar levels of energy that filled half
full.
For example:
8O:1s2 2s2 2px2
2py1 2pz1
Hund’s rule:
The most stable arrangement of electrons in subshells is the one with the
greatest number of parallel spins.
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