Electron configuration

Distribution of electrons in each orbital governed by three rules
  • Aufbau Principle

Charging electrons into each orbital / suborbital adapted to different levels of energy of each orbital
For example: 20Ca : 1s2 2s2 2p6 3s2 3p6 4s2
  •    Pauli Exclusion Principle


Each electron in the atoms just have 1 four quantum numbers (n, l, m and z), if n, l, m equals then s must be different.


Order of orbitals (filling) in multi-electron atom

1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s









Fill lowest energy orbitals first (Aufbau principle)

Fill lowest energy orbitals first (Aufbau principle)





Fill lowest energy orbitals first (Aufbau principle)


  • .    Hund’s Rule

Charging an electron into the orbital / sub-orbital which has the equivalent energy levels may not form the pair first, before orbital who have similar levels of energy that filled half
full.
 For example: 8O:1s2 2s2 2px2 2py1 2pz1
Hund’s rule: The most stable arrangement of electrons in subshells is the one with the greatest number of parallel spins.

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